电邮这篇文章 Triflamidation of Camphene in Nitrile Solutions
- 作者: Sobyanina M.M.1, Garagan I.A.1, Ganin A.S.1
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隶属关系:
- Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
- 期: 卷 60, 编号 8 (2024)
- 页面: 15-22
- 栏目: Articles
- URL: https://www.clinpractice.ru/0514-7492/article/view/676674
- DOI: https://doi.org/10.31857/S0514749224080028
- EDN: https://elibrary.ru/RBFCFX
- ID: 676674
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详细
The reaction of triflamide with camphene in nitrile solutions in the presence of NBS and NIS has been researched. The reactions in isobutyronitrile solution give of various products: dibromide, camphenol, bromamidation product and corresponding amidines. In the reaction in benzonitrile with NBS, two isomeric benzamidines were obtained and isolated. One of them is the product of rearrangement of the camphene framework during the reaction, while in the second one the original substrate structure is retained. When using NIS as an oxidizing agent in the same solvent, a similar mixture of isomers having an iodine atom was obtained.
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作者简介
M. Sobyanina
Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
Email: ganin@irioch.irk.ru
ORCID iD: 0000-0002-0361-0897
俄罗斯联邦, Irkutsk
I. Garagan
Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
Email: ganin@irioch.irk.ru
ORCID iD: 0000-0003-3024-798X
俄罗斯联邦, Irkutsk
A. Ganin
Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: ganin@irioch.irk.ru
ORCID iD: 0000-0003-1626-795X
俄罗斯联邦, Irkutsk
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