Zinc perfluorocyclohexanoate (C6F11COO)2Zn: synthesis, vapor formation and evaluation of thermodynamic characteristics

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Аннотация

The heterophase reaction of interaction of silver perfluorocyclohexanoate with zinc was studied by TG, DSC and mass spectrometry. It was found that as a result of interaction in the temperature range of 320–520 K, solid zinc perfluorocyclohexanoate is formed and an intramolecular reaction of zinc fluoride formation occurs. The obtained experimental data allowed us to calculate the standard enthalpies of formation of the solid zinc complex ΔfН°298.15 = –5693 ± 29 kJ/mol, sublimation and formation of dimeric molecules Zn2(C6F11COO)4 ΔsН°Т = = 190±15 kJ/mol, ΔfН°Т = –11196 ± 40 kJ/mol.

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Авторлар туралы

I. Malkerova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Ресей, Moscow, 119991

D. Kayumova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Ресей, Moscow, 119991

D. Yambulatov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Ресей, Moscow, 119991

A. Khoroshilov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Ресей, Moscow, 119991

A. Sidorov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: alikhan@igic.ras.ru
Ресей, Moscow, 119991

A. Alikhanyan

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: alikhan@igic.ras.ru
Ресей, Moscow, 119991

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2. Fig. 1. Mass loss (wt%) and heat flux (mW/mg) upon heating Ag(C6F11COO) (DSC measurement in red; mass loss in intermittent blue).

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3. Fig. 2. Mass loss (wt%) and heat flux (mW/mg) upon heating of the [Ag(C6F11COO) + Zn] system (DSC measurement in red; mass loss in dashed blue).

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4. Fig. 3. Dependence of the heat of reaction (1) on the mass of silver perfluorocyclohexanoate.

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